Organic Contaminants in Portland Cements Used in Monitoring Well Construction     

Bert Smith  Donald Siegel  Charles Neslund  Charles Carter 《Ground Water Monitoring & Remediation》2014,34(4):102-111

We report the results of two independent laboratory investigations to evaluate total and leachable concentrations of glycols, glycol ethers, phenol, and other compounds in representative Type I and Type I/II Portland cement products that United States Environmental Protection Agency (EPA), The American Society of Testing and Materials (ASTM) and others recommend as annular sealants in monitoring well completions. Water well drillers also use these cements in their well completions. The EPA has included some of these compounds for analysis in their National Hydraulic Fracturing Study to evaluate the effects of hydraulic fracturing on ground‐ and surface water resources. During any contaminant investigation, materials used in monitoring or water well drilling, completion, development, and sampling must be free of the chemicals being targeted by the regulatory agency. Three of five bulk cement products we tested contained part per million (ppm) (mg/kg) concentrations of diethylene glycol, ethylene glycol, tetraethylene glycol, and triethylene glycol; chemicals added as grinding aids during manufacture. Some cements also contained ppb (µg/kg) concentrations of benzoic acid, phenols, propylene glycol, and 2‐butoxyethanol. Leaching of cured cement samples in water produced ppm (mg/L) concentrations of glycols in the supernatant. These results show that cured cements in monitoring or water wells can contaminate groundwater samples with glycols and phenol. Our findings should help prevent future sample bias and false positives when testing for glycol compounds and phenol in groundwater samples from monitoring or water wells and highlight the need to test materials or products used in monitoring or water well drilling, completions, development, and sampling to avoid false positives when sampling and analyzing for less common analytical constituents.  相似文献   

Comprehensive Parametrization of Surface-Layer Transfer Coefficients for Use in Atmospheric Numerical Models   总被引：1，自引：0，他引：1  

Hendrik Wouters  Koen De Ridder  Nicole P. M. van Lipzig 《Boundary-Layer Meteorology》2012,145(3):539-550

A new non-iterative bulk parametrization for surface-layer transfer coefficients for momentum and heat is presented. It is applicable for a wide range of aerodynamic and thermal roughness lengths, and includes the effect of the roughness sublayer. As a consequence, the non-iterative method is suitable for every surface type, especially for urban surfaces for which existing non-iterative parametrizations fail. The analytical approximation compares very well with an iterative approach. Our method can be easily implemented in atmospheric numerical models that already employ a non-iterative approach.  相似文献   

Sensitivity of the Eastern Mediterranean geomorphic system towards environmental change during the Late Holocene: a chronological perspective     

Bert Dusar  Gert Verstraeten  Koen D'haen  Johan Bakker  Eva Kaptijn  Marc Waelkens 《第四纪科学杂志》2012,27(4):371-382

Alluvial and colluvial sediment deposition provide a vital record of environmental change during the Holocene. Firm chronological control on these archives is necessary to enable us to relate sediment dynamics to human activity and climate variability. In the Eastern Mediterranean, such relationships are hard to establish due to the lack of spatially well‐distributed sediment archives with good chronological control. This scarcity is problematic with respect to regional‐scale reconstructions of the temporal variation of sediment dynamics. Here, we present a radiocarbon database (n = 178) of geomorphological activity collected from multiple distinct sediment archives within the territory of Sagalassos in south‐western Turkey. The data were grouped according to their sedimentary facies for analysis using cumulative probability distributions (CPDs) and sedimentation rate (SR) modelling. Two small‐scale colluvial valleys, where chronological information was abundant, were investigated in more detail. Results show that sedimentation chronology differs between individual, nearby cores, as it depends strongly on the local geomorphic situation. A generalizing approach combining multiple core results yields more widely valid conclusions. High sedimentation rates coincided with the initial major anthropogenic disturbance of the landscape and decreased afterwards, probably due to hillslope soil depletion. CPD and SR analysis indicates that in general colluvial sedimentation rates did not change much from 2000 BC onwards. River floodplain sedimentation, in contrast, increased markedly during the first millennium BC and during recent times, and a significant time lag in enhanced sediment deposition between the upper and lower reaches of the river valleys was observed. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

Effects of low-viscous layers and a non-zero obliquity on surface stresses induced by diurnal tides and non-synchronous rotation: The case of Europa     

Hermes M. Jara-Orué  Bert L.A. Vermeersen 《Icarus》2011,215(1):417-438

In this study we present a semi-analytical Maxwell-viscoelastic model of the variable tidal stress field acting on Europa’s surface. In our analysis, we take into account surface stresses induced by the small eccentricity of Europa’s orbit, the non-zero obliquity of Europa’s spin axis - both acting on a diurnal 3.55-days timescale - and the reorientation of the ice shell as a result of non-synchronous rotation (NSR). We assume that Europa’s putative ocean is covered by an ice shell, which we subdivide in a low-viscous and warm lower ice layer (asthenosphere, viscosity 10¹²-10¹⁷ Pa s), and a high-viscous and cold upper ice layer (lithosphere, viscosity 10²¹ Pa s).Viscoelastic relaxation influences surface stresses in two ways: (1) through viscoelastic relaxation in the lithosphere and (2) through the viscoelastic tidal response of Europa’s interior. The amount of relaxation in the lithosphere is proportional to the ratio between the period of the forcing mechanism and the Maxwell time of the high-viscous lithosphere. As a result, this effect is only relevant to surface stresses caused by the slow NSR mechanism. On the other hand, the importance of the viscoelastic response on surface stresses is proportional to the ratio between the relaxation time (τ_j) of a given viscoelastic mode j and the period of the forcing function. On a diurnal timescale the fast relaxation of transient modes related to the low viscosity of the asthenosphere can alter the magnitude and phase shift of the diurnal stress field at Europa’s surface. The effects are largest, up to 20% in magnitude and 7° in phase for ice rigidities lower than 3.487 GPa, when the relaxation time of the aforementioned transient modes approaches the inverse of the average angular rate of Europa’s orbit. On timescales relevant for NSR (>10⁴ years) the magnitude and phase shift of NSR surface stresses can be affected by viscoelastic relaxation of the ocean-ice boundary. This effect, however, becomes only important when the behavior of the lithosphere w.r.t. NSR approaches the fluid limit, i.e. for strong relaxation in the lithosphere. The combination of NSR and diurnal stresses for different amounts of viscoelastic relaxation of NSR stresses in the lithosphere leads to a large variety of global stress fields that can explain the formation of the large diversity of lineament morphologies observed on Europa’s surface. Variation of the amount of relaxation in the lithosphere is likely due to changes in the spin rate of Europa and/or the rheological properties of the surface.In addition, we show that a small obliquity(<1°) can have a considerable effect on Europa’s diurnal stress field. A non-zero obliquity breaks the symmetric distribution of stress patterns with respect to the equator, thereby affecting the magnitude and orientation of the principal stresses at the surface. As expected, increasing the value of Europa’s obliquity leads to larger diurnal stresses at the surface, especially when Europa is located 90° away from the nodes formed by the intersection of its orbital and equatorial planes.  相似文献   

Impact of wind on the spatial distribution of rain over micro‐scale topography: numerical modelling and experimental verification     

Bert Blocken  Jean Poesen  Jan Carmeliet 《水文研究》2006,20(2):345-368

The wind‐driven‐rain effect refers to the redistribution of rainfall over micro‐scale topography due to the existence of local perturbed wind‐flow patterns. Rainfall measurements reported in the literature point to the fact that the wind‐driven‐rain distribution can show large variations over micro‐scale topography. These variations should be taken into account in hillslope hydrology, in runoff and erosion studies and in the design of rainfall monitoring networks. In practice, measurements are often not suitable for determining the wind‐driven‐rain distribution. Therefore, a few researchers have employed numerical modelling. In order to provide confidence in using numerical models, experimental verification for a range of different topographic features is imperative. The objective of this study is to investigate the adequacy of a two‐dimensional Computational Fluid Dynamics (CFD) model to predict the wind‐driven‐rain distribution over small‐scale topography. The numerical model is applied to a number of topographic features, including a succession of cliffs, a small isolated hill, a small valley and a field with ridges and furrows. The numerical results are compared with the corresponding measurement results reported in the literature. It is shown that two‐dimensional numerical modelling can provide a good indication of the wind‐driven‐rain distribution over each type of micro‐scale topography that is considered in this study. It is concluded that more detailed verification procedures are currently inhibited due to the lack of available and detailed spatial and temporal rainfall data from field measurements. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

Present Day Regional Mass Loss of Greenland Observed with Satellite Gravimetry     

E. Schrama  B. Wouters  B. Vermeersen 《Surveys in Geophysics》2011,32(4-5):377-385

This paper summarizes results obtained for Greenland??s mass balance observed with NASA??s GRACE mission. We estimate a Greenland ice sheet mass loss at ?201 ± 19 Gt/year including a discernible acceleration of ?8 ± 7 Gt/year² between March 2003 and February 2010. The mass loss of glacier systems on the South East of Greenland has slowed down while the mass loss increases toward the North along the West side of Greenland. The mass balance can be compared with results obtained by a regional climate model of the Greenland system and ice sheet altimeter data obtained from NASA??s ICEsat mission. Our GRACE-only results differ to within 15% from these independently calculated values; we will comment on the possible causes and the quality of the glacial isostatic adjustment model which is used to correct geodetic datasets.  相似文献   

Scenarios in Global Environmental Assessments: Key characteristics and lessons for future use     

Detlef P. van Vuuren  Marcel T.J. Kok  Bastien Girod  Paul L. Lucas  Bert de Vries 《Global Environmental Change》2012,22(4):884-895

Over the last 10 years a large set of global environmental assessment studies has been published that include scenario projections. Comparison of these studies shows that there is actually a limited set of scenario families that form the basis of many scenarios used in different environmental assessments. Mapping these scenario families allow a simpler comparison across the different assessments. The fact that many assessments can be positioned within these families gives some confidence of their relevance. It is also noticeable that several recent assessments have been focusing on more focussed policy-scenarios as variant to a single baseline. This is partly a response to a different stage in the policy-making process. While there are clear advantages of both categories of scenarios (explorative scenarios and baseline/policy variants), it might be important to test the robustness of scenario outcomes of the policy-scenario approach against the different storyline scenario-families identified in this paper.  相似文献   

Value of perfect ENSO phase predictions for agriculture: evaluating the impact of land tenure and decision objectives     

David Letson  Carlos E. Laciana  Federico E. Bert  Elke U. Weber  Richard W. Katz  Xavier I. Gonzalez  Guillermo P. Podestá 《Climatic change》2009,97(1-2):145-170

In many places, predictions of regional climate variability associated with the El Niño–Southern Oscillation phenomenon offer the potential to improve farmers’ decision outcomes, by mitigating the negative impacts of adverse conditions or by taking advantage of favorable conditions. While the notion that climate forecasts are potentially valuable has been established, questions of when they may be more or less valuable have proven harder to resolve. Using simulations, we estimate the expected value of seasonal climate information under alternative assumptions about (a) land tenure (ownership vs. short-term leases) and (b) the decision maker’s objective function (expected utility vs. prospect theory value function maximization), employing a full range of plausible parameter values for each objective function. This allows us to show the extent to which the value of information depends on risk preferences, loss aversion, wealth levels and expectations, as well as situational constraints. Our results demonstrate in a non-laboratory decision context that, in some cases, psychologically plausible deviations from expected utility maximization can lead to substantial differences in estimates of the expected value of climate forecasts. Efforts to foster effective use of climate information and forecasts in agriculture must be grounded in a firm understanding of the goals, objectives and constraints of decision makers.  相似文献   

Linking hydrological, infinite slope stability and land-use change models through GIS for assessing the impact of deforestation on slope stability in high Andean watersheds   总被引：2，自引：0，他引：2  

Veerle Vanacker  Michiel Vanderschaeghe  Gerard Govers  Edith Willems  Jean Poesen  Jozef Deckers  Bert De Bievre 《Geomorphology》2003,52(3-4):299-315

In the Ecuadorian Andes, episodic slope movements comprising shallow rotational and translational slides and rapid flows of debris and soil material are common. Consequently, not only considerable financial costs are experienced, but also major ecological and environmental problems arise in a larger geographical area. Sediment production by slope movement on hillslopes directly affects sediment transport and deposition in downstream rivers and dams and morphological changes in the stream channels. In developing countries world-wide, slope movement hazards are growing: increasing population pressure and economic development force more people to move to potentially hazardous areas, which are less suitable for agriculture and rangelands.This paper describes the methods used to determine the controlling factors of slope failure and to build upon the results of the statistical analysis a process-based slope stability model, which includes a dynamic soil wetness index using a simple subsurface flow model. The model provides a time-varying estimate of slope movement susceptibility, by linking land-use data with spatially varying hydrologic (soil conductivity, evapotranspiration, soil wetness) and soil strength properties. The slope stability model was applied to a high Andean watershed (Gordeleg Catchment, 250 ha, southern Ecuadorian Andes) and was validated by calculating the association coefficients between the slope movement susceptibility map of 2000 and the spatial pattern of active slope movements, as measured in the field with GPS. The proposed methodology allows assessment of the effects of past and future land-use change on slope stability. A realistic deforestation scenario was presented: past land-use change includes a gradual fragmentation and clear cut of the secondary forests, as observed over the last four decades (1963–2000), future land-use change is simulated based on a binary logistic deforestation model, whereby it was assumed that future land-use change would continue at the same rate and style as over the last 37 years (1963–2000).  相似文献   

Factors determining the longwave radiation exchange over natural surfaces     

D. S. Wouters  H. Keppens  I. Impens 《Theoretical and Applied Climatology》1980,28(1-2):63-71

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